Can u please take a pic? Never seen s mode. mine has D, N, R, P and then manual mode
Another way to describe the function of "S" is to compare it to a manual tranny.
With a manual, while cruising in 4th gear with the engine RPM @ 2200 and you want to pass, but it's a long truck to get around and you want to do it as quickly as possible you do this.
Down shift to 3rd gear and the engine RPM will jump to 3400 RPM, much closer to the power range of an engine, giving you much quicker acceleration and speed than if you just pressed on the gas pedal, waiting for the engine to come up to its power range.
With auto/CVT tranny's, you can press gas pedal to the floor, and it will force the tranny to downshift in a similar manner. The tranny downshifts in response to engine speed and mechanical pressure from the gas pedal.
Unfortunately, under wet conditions this can cause wheel spin and a loose of control due to the engine already revving during the shifting process. Due to traction control features this is mostly a non-issue, but there's always the exceptions.
To alleviate this, manufactures add the ability to downshift manually ("S" Mode) with auto trannys, reducing the possibility of wheel spin, treating it like a manual downshift. Downshifting before the engine revs.
On the 3rd Gen Murano, move the shifter over to manual and then downshift to 5th gear before stepping on the gas pedal when you want to pass, but don't want to slam the gas pedal down. You'll be surprised at how quickly the Murano jumps forward, when asked the right way. Actually, it's kind of fun to pass that way if necessary.
Hopefully this wasn't too long winded and is a little helpful in understanding your Murano.
Have a good day.